Reflective materials look better if your model has something for them to reflect.
The V-ray material library contains a lot of different glass materials. Have you tried different ones?
For more reflection, bump up the ‘IOR’ value. Understand that if you have no ground plane or background then this will just make the interior harder to see but obviously won’t be reflecting anything.
For the tree reflections…easiest way is to just add a tree background from 3D Warehouse and position it so that it’s outside of the camera view(s). Keep in mind that you can play with scale, distance and atmosphere to get the trees to show exactly how you want in the reflections.