Coordinates of points and entering coordinates as edge starting point

Select the label tooltb_label

and click on an endpoint/midpoint. Since version 2019, you can select the tapemeasuretool tb_measure and hover over the points.

Why do you want to do that? Do you know all the vertices from memory?
If you want to do more ‘techsavy’ stuff, learn to place the drawing axis (rightclick on one of the axis and choose ‘move’) and to draw relatively and absolute.

https://help.sketchup.com/en/sketchup/introducing-drawing-basics-and-concepts